摘要

Various annealing conditions were examined for enhancing the electrical conductivity of gallium-doped ZnO (ZnO:Ga) epitaxial films grown from a low-temperature aqueous solution. The resistivity of the films decreased with increasing annealing temperature, accompanying increases in both the carrier concentration and mobility. However, the improvement obtained from 0.5 h of annealing was limited because the films spalled when the temperature exceeded similar to 300 degrees C. The temperature at which spalling of the films occurred depended on the annealing atmosphere, and it was lower in 5%H-2-Ar than in air or vacuum. Thermal desorption spectroscopy showed that the cause of spalling was expulsion of H2O vapor from the interior of the film, indicating that water molecules or hydroxides were incorporated into the crystal during film growth. Analysis of the variations in electrical properties with increasing annealing duration revealed that the electrical properties were quickly improved upon heating before the film spalled. Thus, by limiting the annealing duration to <= 20 s, annealing could be performed at a temperature as high as 580 degrees C without spalling of the film, which yielded the lowest resistivity of 4.7 x 10(-4) Omega cm. The annealed film exhibited transmittance as high as >75% in the visible spectrum.

  • 出版日期2017-4-1