Microflow photo-radical chlorination of cycloalkanes

作者：Matsubara Hiroshi; Hino Yoshiko; Tokizane Masashi; Ryu Ilhyong^*

来源：Chemical Engineering Journal, 2011, 167(2-3): 567-571.

DOI：10.1016/j.cej.2010.08.086

• Microreactor
• Radical chlonnation
• Sulfuryl chloride
• Molecular chlorine
• Photoreaction

Photo-initiated radical chlorination of cycloalkanes was investigated using microflow reactors. Under natural light, microflow chlorination of cyclohexane with molecular chlorine proceeded well to give chlorocyclohexane with high selectivity for single-chlorination. Single-chlorination reaction of cycloalkanes with sulfuryl chloride can also be successfully carried out using a microflow reactor under irradiation using a 15W black light.

• 出版日期2011-3-1