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摘要
In this paper, a ferroferric oxide-reduced graphene oxide (Fe3O4-rGO) composite is prepared by a facile one-step solvothermal method in which the reduction process of graphene oxide (GO) into rGO was accompanied by the generation of Fe3O4 particles without additional molecular linkers and further process. The X-ray diffraction (XRD) pattern of the composite reveals the presence of face-centered cubic Fe3O4. Fourier transform infrared (FTIR) and Raman spectroscopy demonstrate that the GO is reduced to rGO in the solvothermal process. The scanning electron microscopy (SEM) images of the composite indicate that the porous Fe3O4 particles are anchored on rGO sheets with an average diameter of similar to 160 nm, and the amount of Fe3O4 is about 80.7 wt% by thermo-gravimetric (TG) analysis. The Fe3O4-rGO composite exhibits improved cycling stability and rate performances as a potential anode material for high-performance lithium ion batteries (LIBs). It has specific capacities for the first discharge and charge of 1912 and 1450 mA h g(-1), respectively, which is higher than that of pure Fe3O4. Meanwhile, it shows good capacity retention of 1031 mA h g(-1) after 50 cycles, still 84% of the initial capacity. This outstanding electrochemical behaviour can be attributed to the increased electrical conductivity and mechanical stability of Fe3O4 by rGO support during the charging and discharging processes.
