A ternary supramolecular system containing a boronated DNA-metallointercalator, beta-cyclodextrin and the hexanucleotide d(GTCGAC)(2)

作者：Ching H Y Vincent; Buck Damian P; Bhadbhade Mohan; Collins J Grant; Rendina Louis M^*

来源：Chemical communications, 2012, 48(6): 880-882.

DOI：10.1039/c1cc15552k

Solution NMR studies of the interaction between the hexanucleotide d(GTCGAC)(2), beta-cyclodextrin and a boronated 2,2%26apos;:6%26apos;,2 %26apos;%26apos;-terpyridineplatinum(II) complex containing 1,12-dicarba-closo-dodecaborane(12) (1,12-closo-carborane) reveal the formation of a remarkable ternary supramolecular system in which the terpyridine ligand is intercalated between the C-3 and G(4) bases, whilst the closo-carborane moiety is encapsulated by the cyclic sugar.

• 出版日期2012-1-21