2,5,8,11-Tetraboronic Ester Perylenediimides: A Next Generation Building Block for Dye-Stuff Synthesis

作者：Battagliarin Glauco; Li Chen^*; Enkelmann Volker; Muellen Klaus

来源：Organic Letters, 2011, 13(12): 3012-3015.

DOI：10.1021/ol2008457

Via an unprecedentedly reported ruthenium catalyzed reaction, an efficient and straightforward method was developed for the synthesis of 2,5,8,11-tetraboronate perylenediimide derivatives. A possible reaction mechanism is proposed. The synthesis of 2,5,8,11-tetra-lodo and totra-amino perylenedilmides derivatives is also reported.

• 出版日期2011-6-17