Anion-induced dimerization of 5-fold symmetric cyanostars in 3D crystalline solids and 2D self-assembled crystals

作者:Hirsch Brandon E; Lee Semin; Qiao Bo; Chen Chun Hsing; McDonald Kevin P; Tait Steven L*; Flood Amar H
来源:Chemical Communications, 2014, 50(69): 9827-9830.
DOI:10.1039/c4cc03725a

摘要

Anions stabilize stacking of C-5-symmetric macrocycles, called cyanostars, into dimers in solution and herein we demonstrate this stacking in solid-state crystals. We further show that this guest binding can be applied as a route to bilayer growth at the solution-graphite interface.

  • 出版日期2014-9-7