Analysis of bis(trifluoromethylsulfonyl)imide-doped paramagnetic graphite intercalation compound using F-19 very fast magic angle spinning nuclear magnetic resonance

作者：Gotoh Kazuma^*; Takeda Kazuyuki; Lerner Michael M; Sueishi Yoshimi; Maruyama Shinpei; Goto Atsushi; Tansho Masataka; Ohki Shinobu; Hashi Kenjiro; Shimizu Tadashi; Ishida Hiroyuki

来源：Carbon, 2011, 49(12): 4064-4066.

DOI：10.1016/j.carbon.2011.05.009

F atoms bonding to paramagnetic/conductive graphene layers in accepter-type graphite intercalation compounds (GICs) are analyzed using very fast magic angle spinning nuclear magnetic resonance, which is applied for the first time on F-19 nuclei to investigate paramagnetic materials. In the bis(trifluoromethylsulfonyl)imide(TFSI)-doped GIC, C-F bonds between fluorine atoms and graphene layers conform to a weak bonding of F to the graphene sheets. TFSI anions intercalated in the GIC do not show overall molecular motion; even at room temperature only the CF3 groups rotate.

• 出版日期2011-10