Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte

作者：Starodubtseva Eugenia V; Turova Olga V; Vinogradov Maxim G^*; Ferapontov Vladimir A; Razmanov Ilya V; Zlotin Sergei G; Kucherenko Alexander S

来源：Mendeleev Communications, 2007, 17(1): 20-21.

DOI：10.1016/j.mencom.2007.01.008

The asymmetric hydrogenation of methyl levulinate to chiral gamma-valerolactone has been performed with the recycling of a Ru-II-BINAP catalyst deposited on a solid organic polyelectrolyte; enantioselectivity up to 99% ee has been achieved at high conversion of substrate after three recycles of the catalyst.

• 出版日期2007-2