UV-VIS Absorption Spectra of Molten AgCl and AgBr and of their Mixtures with Group I and II Halide Salts

作者:Greening Giorgio G W*
来源:Zeitschrift fur Naturforschung Section A-A Journal of Physical Sciences, 2015, 70(10): 787-790.
DOI:10.1515/zna-2015-0197

摘要

The UV-VIS absorption spectra of (Ag1-X [Li-Cs, Ba](X))Cl and of (Ag1-X[Na, K, Cs](X))Br at 823 K at the concentrations X = 0.0, 0.1, 0.2 have been measured. The findings show that on adding the respective halides to molten silver chloride and silver bromide, shifts of the fundamental absorption edge to shorter wavelengths result. A correlation between the observed shifts and the expansion of the silver sub-lattice is found, which is valid for both silver halide systems studied in this work.

  • 出版日期2015-10

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