A new diamantane functionalized tris(aryloxide) ligand system for small molecule activation chemistry at reactive uranium complexes

作者：Lam Oanh P; Heinemann Frank W; Meyer Karsten^*

来源：Comptes Rendus Chimie, 2010, 13(6-7): 803-811.

DOI：10.1016/j.crci.2010.03.004

• Uranium
• Tripodal ligands
• Chelates
• Macrocyclic
• Diamantane

The diamantane functional ized triazacyclononane ligand ((Dia)ArOH)(3)tacn (L(3)) has been synthesized and the reactivity of its U(III) metallated product [(((Dia)ArO)(3)tacn)U] (1) has been explored. Complex 1 promotes dichloromethane and azidotrimethylsilane activation to generate U(IV) complex [(((Dia)ArO)(3)tacn)U(Cl] (2) and U(V) complex 1(((Dia)ArO)(3)tacn)U(NTMS)] (3), respectively.

• 出版日期2010-7