A simple method for epoxidation of olefins using sodium chlorite as an oxidant without a catalyst

作者：Geng, XL; Wang, Z; Li, XQ; Zhang, C^*

来源：Journal of Organic Chemistry, 2005, 70(23): 9610-9613.

DOI：10.1021/jo0511400

• MANGANESE-CONTAINING POLYOXOMETALATE
• 30-PERCENT HYDROGEN-PEROXIDE
• GENERATED IN-SITU
• CARBOXYLIC-ACIDS
• EFFICIENT EPOXIDATION
• AROMATIC CHLORINATION
• ALKENE EPOXIDATION
• TERMINAL OLEFINS
• OXIDATION
• ALUMINA

Sodium chlorite has been demonstrated to be capable of epoxidizing a variety of olefins at 55-65 degrees C (oil bath). Chlorine dioxide is believed to be the pivotal epoxidizing agent in the reaction on the basis of the mechanistic studies.

• 出版日期2005-11-11
• 单位元素有机化学国家重点实验室; 南开大学