Hydrogen-Treated Rutile TiO2 Shell in Graphite-Core Structure as a Negative Electrode for High-Performance Vanadium Redox Flow Batteries

作者：Vazquez Galvan Javier; Flox Cristina; Fabrega Cristian; Ventosa Edgar; Parra Andres; Andreu Teresa; Ramon Morante Joan

来源：Chemsuschem, 2017, 10(9): 2089-2098.

DOI：10.1002/cssc.201700017

• hydrogen evolution reaction
• oxygen vacancies
• redox flow batteries
• titanium dioxide
• vanadium

Hydrogen-treated TiO2 as an electrocatalyst has shown to boost the capacity of high-performance all-vanadium redox flow batteries (VRFBs) as a simple and eco-friendly strategy. The graphite felt-based GF@TiO2:H electrode is able to inhibit the hydrogen evolution reaction (HER), which is a critical barrier for operating at high rate for long-term cycling in VRFBs. Significant improvements in charge/discharge and electron-transfer processes for the V3+/V2+ reaction on the surface of reduced TiO2 were achieved as a consequence of the formation of oxygen functional groups and oxygen vacancies in the lattice structure. Key performance indicators of VRFB have been improved, such as high capability rates and electrolyte-utilization ratios (82% at 200mAcm(-2)). Additionally, high coulombic efficiencies (ca. 100% up to the 96thcycle, afterwards >97%) were obtained, demonstrating the feasibility of achieving long-term stability.

• 出版日期2017-5-9