A 1D Helical Ni(II) Coordination Polymer Based on Butylphenyl Imidazole Dicarboxylate

作者：Liu Shaofeng; Wang Beibei; Guo Mengwei; Li Gang^*

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2015, 45(5): 719-724.

DOI：10.1080/15533174.2013.841239

• coordination polymer
• Ni(II)
• crystal structure
• imidazole dicarboxylate
• property

Solvothermal reaction of nitrate salt with a multifunctional organic ligand, 2-(p-tert-butylphenyl)-1H-imidazole-4,5-dicarboxylic acid (p-H3BuPhIDC), leads to a novel 1-D helical chain coordination polymer, {[Ni-4(mu(2)-p-HBuPhIDC)(4)(H2O)(4)]center dot H2O}(n) (1), which has been characterized by single-crystal X-ray diffraction, spectroscopy, and elemental analysis. The thermal and photoluminescent properties of polymer 1 have been investigated as well.

• 出版日期2015
• 单位郑州大学