Novel Synthesis and Crystal Structure of 2-(4-Methylphenyl)-3-ferrocenyl-4,4-dicyanpyrrolizidine

作者：Liu Peng; Zhang Yu Mei^*; Zhang Hong Li; Geng Li Jun

来源：Chinese Journal of Structural Chemistry, 2013, 32(6): 853-856.

DOI：10.14102/j.cnki.0254-5861.2013.06.009

• ferrocene
• pyrrolizidine
• synthesis
• crystal structure

A novel ferroenyl pyrrolizidine derivative containing cyano groups, 2-(4-methylphenyl)-3-ferrocenyl-4,4-dicyanpyrrolizidine (C26H25FeN3, M-r = 435.34), was synthesized in moderate yields via a facile 1.3-dipolar cycloaddition in refluxing toluene and its crystal structure was determined by single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P2(1)/c with a = 10.3792(10), b = 11.4485(11), c = 19.1243(15) angstrom, beta = 109.496(4)degrees, V = 2142.2(3) angstrom(3), D-c = 1.350 g/cm(3), mu(MoK alpha) = 0.721 mm(-1), Z = 4, T = 113(2) K, F(000) = 912, the final R = 0.0586 and wR = 0.1664.

• 出版日期2013
• 单位河北大学