A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

作者：Sheu Chou Fu; Shih Che Hsiu; Sugimoto Kunihisa; Cheng Bing Ming; Takata Masaki; Wang Yu^*

来源：Chemical communications, 2012, 48(46): 5715-5717.

DOI：10.1039/c2cc31326j

In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe-II(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.

• 出版日期2012