A luminescent single-molecule magnet: observation of magnetic anisotropy using emission as a probe

作者：Yamashita Kei; Miyazaki Rie; Kataoka Yumiko; Nakanishi Takayuki; Hasegawa Yasuchika^*; Nakano Motohiro; Yamamura Tomoo; Kajiwara Takashi

来源：Dalton Transactions, 2013, 42(6): 1987-1990.

DOI：10.1039/c2dt32785f

An assemblage of a Tb(III) ion and two mononuclear [Zn-II(L)] complexes as antenna chromophores (H2L: Schiff base ligand) afforded a luminescent single-molecule magnet. The f-f emission spectrum had partially resolved fine structure which provides detailed information on the magnetic anisotropy of the F-7(6) ground multiplet of the Tb(III) ion.

• 出版日期2013