Atropurpuran-missing biosynthetic link leading to the hetidine and arcutine C-20-diterpenoid alkaloids or an oxidative degradation product?

作者：Weber Manuel; Owens Kyle; Sarpong Richmond^*

来源：Tetrahedron Letters, 2015, 56(23): 3600-3603.

DOI：10.1016/j.tetlet.2015.01.111

• Biosynthesis
• Diterpenoid alkaloids
• Hetidine
• Arcutines
• Oxidation

A possible biosynthetic link between atropurpuran, the hetidine diterpenoid alkaloids and the alkaloid arcutine and congeners is proposed. The feasibility of aspects of this biosynthesis, especially key 1,2-rearrangements, have been examined computationally.

• 出版日期2015-6-3