Second-Order Nonlinear Optical Properties of Polyoxometalate Salts of a Chiral Stilbazolium Derivative

作者:Compain Jean Daniel; Mialane Pierre; Dolbecq Anne*; Marrot Jerome; Proust Anna; Nakatani Keitaro; Yu Pei; Secheresse Francis
来源:Inorganic Chemistry, 2009, 48(13): 6222-6228.
DOI:10.1021/ic900519p

摘要

A chiral center has been introduced to an organic cation to force the crystallization of polyoxometalate (POM)-based molecular materials in a noncentrosymmetric space group. The charge-transfer salt of this chiral cation with a Keggin anion exhibits a second harmonic generation efficiency 10 times better than those of the other nonlinear optical salts with POMs previously reported.

  • 出版日期2009-7-6