A novel cadmium imidazolate framework (CdIF) with ice-XII structure of itv topology

作者:Li, Yan-Tao; Yao, Shi-Yan; Wang, Yan; Cui, Ke-Hui; Li, Hai-Qin; Wang, Xin; Zhu, Jian-Qi; Li, Jia; Tian, Yun-Qi*
来源:CrystEngComm, 2011, 13(10): 3470-3473.
DOI:10.1039/c1ce05055a

摘要

A novel cadmium imidazolate framework of [Cd(nim)(2)] (CdIF-13, nim 2-nitroimidazolate) has been prepared and structurally characterized that demonstrates a self-penetrating 4-connected net identified with the ice XII structure of itv topology and is presented as the first metal-organic framework (MOF) with itv topology and the second metal imidazolate framework (MIF) with self-penetrating and ice-like structure.