Gold-catalyzed intermolecular oxidation of o-alkynylbiaryls: an easy and practical access to functionalized fluorenes

作者：Pan, Fei; Liu, Shuang; Shu, Chao; Lin, Rong-Kun; Yu, Yong-Fei; Zhou, Jin-Mei; Ye, Long-Wu^*

来源：Chemical Communications, 2014, 50(73): 10726-10729.

DOI：10.1039/c4cc05115g

• EFFICIENT SYNTHESIS
• CYCLIZATION
• DERIVATIVES
• CYCLOISOMERIZATION
• CARBENES
• CYCLOPROPANATION
• PHENANTHRENES
• REARRANGEMENT
• CLEAVAGES
• ASTERISK

A novel gold-catalyzed intermolecular oxidation of o-alkynylbiaryls has been developed. A variety of functionalized fluorenes are readily accessed by utilizing this non-diazo approach, thus providing a viable alternative to synthetically useful fluorenes.

• 出版日期2014
• 单位厦门大学