Dithiophene-Fused Tetracyanonaphthoquinodimethanes (DT-TNAPs): Synthesis and Characterization of pi-Extended Quinoidal Compounds for n-Channel Organic Semiconductor

作者：Yanai Naoyuki; Mori Takamichi; Shinamura Shoji; Osaka Itaru; Takimiya Kazuo^*

来源：Organic Letters, 2014, 16(1): 240-243.

DOI：10.1021/ol403234q

Dithiophene-fused tetracyanonaphthoquinodimethanes (DTTNAPs) were synthesized and evaluated as n-channel organic semiconductors. DTTNAPs, regardless of isomeric structures and substituents, have low-lying LUMO energy levels (similar to 4.6 eV below the vacuum level), suitable for stable n-channel field-effect transistors (FETs) under ambient conditions. In fact, alpha-DTTNAP derivatives afforded solution-processed FETs showing an electron mobility of 10(-3) cm(-2) V-1 s(-1), indicating that DTTNAPs are a potential molecular framework for channel organic semiconductors.

• 出版日期2014-1-3