Molecular phase engineering of organic semiconductors based on a [1]benzothieno[3,2-b] [1]benzothiophene core

作者：He, Yaowu; Xu, Wenjun; Murtaza, Imran; Zhang, Dongwei; He, Chao; Zhu, Yanan; Meng, Hong^*

来源：RSC Advances, 2016, 6(97): 95149-95155.

DOI：10.1039/c6ra22999a

• FIELD-EFFECT TRANSISTORS
• SET MODEL CHEMISTRY
• HIGH-PERFORMANCE
• LIQUID-CRYSTAL
• TOTAL ENERGIES
• MOBILITIES

Two environmentally and thermally stable [1] benzothieno[3,2-b][1] benzothiophene (BTBT) derivatives, 2-phenyl[1]benzothieno[3,2-b][1]benzothiophene (Ph-BTBT) and 2-(4-hexylphenyl)[1]benzothieno[3,2-b][1] benzothiophene (C6-Ph-BTBT), are prepared by Suzuki coupling. Organic thin-film transistors with a top-contact and bottom-gate based on BTBT, Ph-BTBT and C6-Ph-BTBT are fabricated by vacuum-deposition on octyltrichlorosilane treated Si/SiO2 substrates. Experimental results show that the thin-film based on BTBT sublimes instantly after the deposition of electrodes, and no semiconductor signal is detected. Ph-BTBT shows a mobility of 0.034 cm(2) V-1 s(-1). Furthermore, C6-Ph-BTBT exhibits three liquid crystal phases (Sm A, Sm E and Sm K or H) and achieves the highest hole mobility of 4.6 cm(2) V-1 s(-1) with an on/off ratio of 2.2 x 10(7) for polycrystalline organic thin-film transistors in ambient air. The present study exemplifies that the introduction of mesoscopic order in molecular design provides a general approach for the high electronic performance of organic semiconductors.

• 出版日期2016
• 单位北京大学深圳研究生院; 南京工业大学; 北京大学