Novel two-step SnO(2)/Sno water-splitting cycle for solar thermochemical production of hydrogen

作者：Abanades Stephane^*; Charvin Patrice; Lemont Florent; Flamant Gilles

来源：International Journal of Hydrogen Energy, 2008, 33(21): 6021-6030.

DOI：10.1016/j.ijhydene.2008.05.042

• Hydrogen
• Thermochernical cycle
• Water-splitting
• Tin oxide
• Solar energy

The production of hydrogen from a novel two-step thermochemical cycle based on SnO(2)/Sno redox reactions is presented. This process targets CO(2)-free hydrogen production by using renewable solar energy and water in a high-temperature water-splitting cycle. The cycle consists of a solar endothermic reduction of SnO(2) into SnO(g) and O(2) followed by a non-solar exothermic hydrolysis of SnO(s) to form H(2) and SnO(2)(S). The objective of this study was to demonstrate this innovative concept for H(2) production and to establish the potential of cycle implementation in an integrated solar chemical process. The reduction and hydrolysis reactions were experimentally tested in order to define optimal operating conditions, chemical conversion and hydrogen yield. The thermal reduction occurs under atmospheric pressure at about 1600 degrees C and over. The solar step encompasses the formation of Sno nanoparticles that can be hydrolysed efficiently in the temperature range 500-600 degrees C with a H(2) yield over 90%. A preliminary process design is also proposed for cycle integration in solar chemical plants.

• 出版日期2008-11
• 单位中国地震局