Dramatic effect of redox pre-treatments on the CO oxidation activity of Au/Ce0.50Tb0.12Zr0.38O2-x catalysts prepared by deposition-precipitation with urea: a nano-analytical and nano-structural study

作者:del Rio Eloy*; Lopez Haro Miguel; Cies Jose M; Delgado Juan J; Calvino Jose J; Trasobares Susana; Blanco Ginesa; Cauqui Miguel A; Bernal Serafin
来源:Chemical Communications, 2013, 49(60): 6722-6724.
DOI:10.1039/c3cc42051e

摘要

Nano-structural and nano-analytical studies show that the dramatic difference in CO oxidation activity observed between two Au/Ce0.50Tb0.12Zr0.38O2-x samples prepared by deposition-precipitation with urea and further activated under oxidising or reducing conditions is due to the poisoning effect of a very thin layer of carbon grown on the pre-reduced catalyst.

  • 出版日期2013