Asymmetric total synthesis and revision of absolute configurations of azaphilone derivative felinone A

作者：Abe Hideki^*; Tango Haruhito; Kobayashi Toyoharu; Ito Hisanaka^*

来源：Tetrahedron Letters, 2017, 58(45): 4296-4298.

DOI：10.1016/j.tetlet.2017.09.090

• Felinone A
• Asymmetric total synthesis
• Revision of absolute configurations
• Intramolecular oxymercuration/demercuration
• Shi epoxidation

The first total synthesis of the azaphilone derivative, felinone A, was accomplished. The absolute configuration of natural felinone A was revised to be 3S, 6S, and 7R.

• 出版日期2017-11-8