A Self-Doping, O2-Stable, n-Type Interfacial Layer for Organic Electronics

作者：Reilly Thomas H III^*; Hains Alexander W; Chen Hsiang Yu; Gregg Brian A

来源：Advanced Energy Materials, 2012, 2(4): 455-460.

DOI：10.1002/aenm.201100446

• doping
• organic electronics
• photovoltaic devices
• solar cells
• thin films

Solid films of a water-soluble dicationic perylene diimide salt, perylene bis(2-ethyltrimethylammonium hydroxide imide), Petma+OH-, are strongly doped n-type by dehydration and reversibly de-doped by hydration. The hydrated films consist almost entirely of the neutral perylene diimide, PDI, while the dehydrated films contain similar to 50% PDI anions. The conductivity increases by five orders of magnitude upon dehydration, probably limited by film roughness, while the work function decreases by 0.74 V, consistent with an n-type doping density increase of similar to 12 orders of magnitude. Remarkably, the PDI anions are stable in dry air up to 120 degrees C. The work function of the doped film, ? (3.96 V vs. vacuum), is unusually negative for an O2-stable contact. Petma+OH- is also characterized as an interfacial layer, IFL, in two different types of organic photovoltaic cells. Results are comparable to state of the art cesium carbonate IFLs, but may improve if film morphology can be better controlled. The films are stable and reversible over many months in air and light. The mechanism of this unusual self-doping process may involve the change in relative potentials of the ions in the film caused by their deshielding and compaction as water is removed, leading to charge transfer when dry.

• 出版日期2012-4