Nitrogen doped activated carbon from pea skin for high performance supercapacitor

作者：Ahmed Sultan; Ahmed Ahsan; Rafat M

来源：Materials Research Express, 2018, 5(4): 045508.

DOI：10.1088/2053-1591/aabbe7

• biomass
• nitrogen doping
• activated carbon
• electrode
• electrolyte
• supercapacitor

In this work, nitrogen doped porous carbon (NDC) has been synthesized employing a facile two-step process. Firstly, carbon precursor (pea skin) was heated with melamine (acting as nitrogen source) followed by activation with KOH in different ratios. The dependence of porosity and nitrogen content on impregnation ratio was extensively studied. Other textural properties of prepared NDC sample were studied using standard techniques of material characterization. The electrochemical performance of NDC sample as an electrode was studied in two-electrode symmetric supercapacitor system. 1M LiTFSI (lithium bis-trifluoromethanesulfonimide) solution in IL EMITFSI (1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide), was used as electrolyte. It was found that the fabricated supercapacitor cell offers high values of specific capacitance (141.1 F g(-1)), specific energy (19.6Wh kg(-1)) and specific power (25.4 kW kg(-1)) at current density of 1.3 A g(-1). More importantly, the fabricated supercapacitor cell shows capacitance retention of similar to 75%, for more than 5000 cycles. The enhanced performance of NDC sample is primarily due to large surface area with favorable surface structure (contributing to double layer capacitance) and presence of nitrogen functionalities (contributing to pseudo-capacitance). Such important features make the synthesized NDC sample, an attractive choice for electrode material in high performance supercapacitor.

• 出版日期2018-4