Distinct Chain/Layer Structures in Silver(I) Compounds: Synthesis, Structures, and Photoluminescent Properties

作者：Zhang, Xin; Huang, Yuan-Yuan; Liu, Zi-Sheng; Yao, Yuan-Gen^*

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2012, 638(6): 1042-1046.

DOI：10.1002/zaac.201200025

• Diphenic acid
• Coordination polymer
• Argentophilic interaction
• Silver
• Photoluminescence

Two new hybrid inorganic-organic compounds with different chain/layer structures, [Ag(bipy)]n center dot n(Hdpa)center dot n(DMF)center dot n(H2O) (1) and [Ag(dpa)0.5(bix)0.5]n (2) [H2dpa = diphenic acid, bipy = 4, 4'-bipyridine, bix = 4, 4'-bis(imidazol-1-ylmethyl)benzene, DMF = N,N'-dimethylformamide] were successfully synthesized and characterized by elemental analysis, IR spectroscopy, and powder X-ray diffraction. Single X-ray analysis reveals that compound 1 is a one-dimensional (1D) supramolecular double chain structure constructed by the combination of coordination bonds, hydrogen bonds, weak Ag center dot O and argentophilic interactions, compound 2 is a two-dimensional (2D) undulated layer structure constructed by coordination bonds, weak Ag center dot O and argentophilic interactions. Moreover, the photoluminescent properties of the two compounds were also investigated in the solid state at room temperature.

• 出版日期2012-5
• 单位中国科学院福建物质结构研究所