Homogeneous catalytic dimerization of propylene with bis(imino)pyridine vanadium(III) complexes

作者：Lang Julian R V; Denner Christine E; Alt Helmut G^*

来源：Journal of Molecular Catalysis A: Chemical , 2010, 322(1-2): 45-49.

DOI：10.1016/j.molcata.2010.02.013

• Homogeneous catalyst
• Vanadium
• Bis(imino)pyridine
• Propylene
• Dimerization

A series of new bis(imino)pyridine vanadium(III) complexes was synthesized. They were tested for the homogeneous catalytic dimerization of propylene after activation with MAO. The activity and selectivity depend on the ligand structure of the corresponding organic coordination compound. The influence of PPh(3) as an additive was investigated and high dependency could be observed.

• 出版日期2010-5-1