Beyond click chemistry: spontaneous C-triazolyl transfer from copper to rhenium and transformation into mesoionic C-triazolylidene carbene

作者:Alvarez Celedonio M; Garcia Escudero Luis A; Garcia Rodriguez Raul; Miguel Daniel*
来源:Chemical communications, 2012, 48(57): 7209-7211.
DOI:10.1039/c2cc32725b

摘要

The exceptional versatility of the 1,2,3-triazole ring in tridentate carbonyl rhenium complexes has been explored starting from a %26quot;click chemistry%26quot; unexpected product obtained from the spontaneous copper to rhenium transmetalation, which opens the way to successive transformation to C-triazolyl and triazolylidene mesoionic carbene.

  • 出版日期2012