A three-dimensional metal-organic framework with a pcu net constructed by zinc(II)/3-amino-1,2,4-triazole layer and an inorganic sulfate pillar

作者：Lin, Jian-Di; Huang, Zhi-Jian; Xie, Yong-Ping; Li, Qing-Lu^*

来源：Journal of Molecular Structure, 2015, 1083: 163-167.

DOI：10.1016/j.molstruc.2014.11.050

• Coordination polymer
• Inorganic sulfate pillar
• Crystal structure
• Topological analysis
• Photoluminescent

Hydrothermal reaction of ZnSO4 center dot 7H(2)O and 3-amino-1H-1,2,4-triazole (HATRZ) led to a three-dimensional zinc(II) coordination polymer, Zn-2(ATRZ)(2)SO4 center dot 3H(2)O (1). Compound 1 has been fully characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, infrared spectroscopy and elemental analysis. Single crystal X-ray diffraction reveals that 1 is a pcu-like network metal-organic framework which is constructed by a zinc(II)/ATRZ layer and a rarely reported inorganic sulfate pillar. Moreover, 1 shows characteristic ligand-centered fluorescence property.

• 出版日期2015-3-5
• 单位福建农林大学