Ultrafast Magic-Angle Spinning: Benefits for the Acquisition of Ultrawide-Line NMR Spectra of Heavy Spin-1/2 Nuclei

作者：Poeppler Ann Christin; Demers Jean Philippe^*; Malon Michal; Singh Amit Pratap; Roesky Herbert W; Nishiyama Yusuke^*; Lange Adam^*

来源：ChemPhysChem, 2016, 17(6): 812-816.

DOI：10.1002/cphc.201501136

• chemical shift anisotropy
• heavy spin 1/2 nuclei
• magic angle spinning
• NMR spectroscopy
• tin

The benefits of the ultrafast magic-angle spinning (MAS) approach for the acquisition of ultrawide-line NMR spectraspectral simplification, increased mass sensitivity allowing the fast study of small amounts of material, efficient excitation, and application to multiple heavy nucleiare demonstrated for tin(II) oxide (SnO) and the tin complex [(LB)(SnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) [LB=2,6-diacetylpyridinebis(2,6-diisopropylanil)] containing two distinct tin environments. The ultrafast MAS experiments provide optimal conditions for the extraction of the chemical-shift anisotropy tensor parameters, anisotropy, and asymmetry for heavy spin-1/2 nuclei.

• 出版日期2016-3-16