Degradation of Rhodamine B by persulfate activated with Fe3O4: Effect of polyhydroquinone serving as an electron shuttle

作者：Leng Yanqiu; Guo Weilin^*; Shi Xiao; Li Yingyun; Wang Anqi; Hao Feifei; Xing Liting

来源：Chemical Engineering Journal, 2014, 240: 338-343.

DOI：10.1016/j.cej.2013.11.090

• Fe3O4 magnetic nanoparticles
• Rhodamine B
• Sulfate radical
• Polyhydroquinone
• Electron shuttle

Polyhydroquinone, an immobilized quinone, was synthesized by oxidative polymerization of hydroquinone. The polymers obtained were characterized by Fourier-transform infrared spectra and cyclic voltammetry. Polyhydroquinone is a redox-active polymer with quinone/hydroquinone redox active units in the main chain. The influence of polyhydroquinone in the Fe3O4/persulfate system was examined. It was found that the addition of polyhydroquinone in Fe3O4/persulfate system increased the oxidation rate of Rhodamine B (RhB), which was ascribed to their role as an electron shuttle. The presence of polyhydroquinone successfully builds up two cycles, one semiquinone/quinone cycle, another cycle of Fe(III)/Fe(II) induced by quinone. The presence of phenolic and quinonoid moieties in the structure of polyhydroquinone provide for their ability to reduce Fe(III), thereby assisting the redox cycling of Fe and increasing degradation of the target substrate.

• 出版日期2014-3-15
• 单位济南大学