Aqua[N-(1-naphthyl)acetamido-kappa N]bis-[2-(2-pyridyl)phenyl-kappa(2) N,C-1] iridium(III) ethylene glycol hemisolvate

作者:Fu Hao; Ding Yuqiang*; Chen Guoqing
来源:Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M731-U1017.
DOI:10.1107/S1600536808010040

摘要

In the title compound, [Ir(C11H8N)(2)(C12H10NO)(H2O)] .-0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyridyl)phenyl (ppy) ligands, one N atom from the N-(1-naphthyl)acetamide ligand and one water O atom, forming a distorted octahedral environment. Molecules are linked by intermolecular O-H center dot center dot center dot O hydrogen bonds formed by the coordinated water molecule and the amide O atom of the N-(1-naphthyl) acetamide ligands.