Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent ladders observed for [M-2(4,4 '-bpy)(3)(H2O)(2)(phba)(2)](NO3)(2)center dot 4H(2)O (M = Cu2 or Co2 ; 4,4 '-bpy=4,4 '-bipyridine; phba=4-hydroxybenzoate)

作者：Tong, ML; Chen, HJ; Chen, XM^*

来源：Inorganic Chemistry, 2000, 39(10): 2235-+.

DOI：10.1021/ic991312+

isomorphous molecular ladders formulated as [M-2- (4,4'-bpy)(3)(phba)(2)(H2O)(2)](NO3)(2). 4H(2)O (4,4'-bpy = 4,4'-bipyridine; phba = 4-hydroxybenzoate; M = Cu2 Or Co2 ), shown by X-ray, feature a novel ladder motif having different inner rungs (4,4'-bpy) and lateral arms (phba). Penetration of the lateral arms into the squares of adjacent ladders results in a novel 3-D network.

• 出版日期2000-5-15
• 单位中山大学