Partial oxidation of methane on Ni(x)AlBEA and Ni(x)SiBEA zeolite catalysts: Remarkable effect of preparation procedure and Ni content

作者：Chalupka Karolina A^*; Jozwiak Wojciech K; Rynkowski Jacek; Maniukiewicz Waldemar; Casale Sandra; Dzwigaj Stanislaw

来源：Applied Catalysis B: Environmental , 2014, 146: 227-236.

DOI：10.1016/j.apcatb.2013.05.007

• POM reaction
• Synthesis gas
• Ni catalysts
• BEA zeolite

This work reports on the investigation of the influence of the preparation procedure and Ni content on partial oxidation of methane to synthesis gas. For this purpose the Ni-containing zeolite catalysts were prepared by two different methods: a conventional wet impregnation method (Ni(x)AlBEA series), in which Ni ions were introduced mainly in the extra framework position and a two-step postsynthesis method (Ni(x)SiBEA series), which allowed incorporating Ni ions into the zeolite framework. Calcined Ni(x)AIBEA and Ni(x)SiBEA zeolite catalysts showed different physicochemical properties and thermal stability in POM reaction. The C-Ni(x)SiBEA catalysts demonstrated very high activity (100% conversion of CH4) and selectivity to CO (up to 100%) and resistance to deactivation. Moreover, they were much more stable than C-Ni(x)AlBEA catalysts. On neither of 2 series of catalysts carbon deposition was observed in contrast to the catalysts usually used and described in literature. The TPR-H-2 experiments showed the presence of different Ni species in C-Ni(x)SiBEA and C-Ni(x)AlBEA catalysts and XRD analysis proved that dealumination and high temperature treatment did not destroy the zeolite structure.

• 出版日期2014-3