科研之友
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摘要
A novel complex 1 of {[Ag(bpp)(dcpa)]H2O}(n) [Hdcpa: 2,6-dichlorophenylacetic acid; bpp: 1,3-bis(4-pyridyl)propane] was synthesized and characterized by elemental analysis, IR, TGA, X-ray single crystal diffraction. The carboxylate oxygens of the Hdcpa ligands connect one Ag(I) ion in bidentate chelating mode to form mononuclear silver building blocks, which are into a 1D infinite chain through trans-bpp ligands. A two-dimensional network consist of adjacent Ag-bpp chain through Ag-Ag interaction. Furthermore, the luminescent property of complex 1 was investigated at room temperature. CCDC: 996495.
