A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et(2)(2)(timdt ligand (Et)timdt = monoreduced diethylimidazolidine-2,4,5-trithione)

作者：Aragoni MC; Arca M^*; Denotti C; Devillanova FA; Grigiotti E; Isaia F; Laschi F; Lippolis V; Pala L; Slawin AMZ; Zanello P; Woollins JD

来源：European Journal of Inorganic Chemistry, 2003, (7): 1291-1295.

• palladium
• halogenation
• S ligands
• density functional calculations
• nonlinear optics

The reaction of the dithiolene [Pd(Et(2)timdt)(2)] (Et(2)timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br-2 or IBr yields the complex [Pd(Et(2)timdt)Br-2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et(2)timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported.

• 出版日期2003-4