Assembly of a phospho-molybdic Wells-Dawson-based silver coordination polymer derived from Keggin polyoxoanion cluster

作者：Dang, Dong-Bin; An, Bing; Bai, Yan^*; Niu, Jing-Yang

来源：Dalton Transactions, 2012, 41(45): 13856-13861.

DOI：10.1039/c2dt30476g

• METAL-ORGANIC FRAMEWORK
• AG-I INTERACTIONS
• POLYOXOMETALATE CLUSTERS
• COMPLEXES
• LIGANDS
• ANIONS
• UNITS
• 2D

A 2D Wells-Dawson-based silver(I) coordination polymer was achieved based on silver-Schiff base building blocks and [P2Mo18O62](6-) clusters using AgNO3, N,N'-bis(furan-2-ylmethylene)hydrazine and Keggin [PMo12O40](3-) as original materials at room temperature. It is structurally characterized by IR spectroscopy, P-31 NMR, XRPD, thermogravimetric (TG) analyses and X-ray crystallography. The structure of 1 exhibits a novel crystalline 2D coordination polymer constructed by the coordination interaction between the Wells-Dawson polyoxoanion [P2Mo18O62](6-) and Ag-L species. The luminescent property of 1 in the solid state is investigated.

• 出版日期2012
• 单位河南大学