Stereoselective synthesis of zoanthenol ABC-ring by radical strategy

作者：Yamashita Shuji^*; Suda Naoki; Hayashi Yujiro; Hirama Masahiro

来源：Tetrahedron Letters, 2013, 54(11): 1389-1391.

DOI：10.1016/j.tetlet.2012.12.104

• Marine natural product
• Zoanthenol
• Tandem radical cyclization
• Atom transfer

Zoanthenol, isolated from Zoanthus sp., possesses an extremely complex architecture including congested quaternary carbons. We describe a concise synthesis of the fully functionalized ABC-ring of zoanthenol based on sequential radical reactions.

• 出版日期2013-3-13