Melamine-terephthalaldehyde-lithium complex: a porous organic network based single ion electrolyte for lithium ion batteries

作者：Rohan Rupesh; Pareek Kapil; Cai Weiwei; Zhang Yunfeng; Xu Guodong; Chen Zhongxin; Gao Zhiqiang; Dan Zhao; Cheng Hansong^*

来源：Journal of Materials Chemistry A, 2015, 3(9): 5132-5139.

DOI：10.1039/c4ta06855f

Cationic transference number and ionic conductivity of an electrolyte are among the key parameters that regulate battery performance. In the present work, we introduce a novel concept of using porous organic frameworks as a single ion-conducting electrolyte for lithium ion batteries. The synthesized lithium functionalized melamine-terephthalaldehyde framework (MTF-Li), a three dimensional porous organo-lithium complex, in a medium of organic solvent exhibits ionic conductivity comparable to the values of typical gel polymer electrolytes, and the battery cell assembled with the membrane of the material performs at both room temperature and at 80 degrees C. The rigid three-dimensional framework, functioning as the anionic part of the electrolyte, reduces the anionic transference number to a minimum. As a consequence, the cationic transference number increases to 0.88, close to unity. In addition, by virtue of its synthesis procedure, the electrolyte displays excellent sustainability at high temperatures, which is important for battery safety as well as for enhancing the performance and longevity of the battery.

• 出版日期2015
• 单位中国地质大学（北京）