alpha-PHOSPHINO AMINO ACIDS: SYNTHESIS, STRUCTURE, AND REACTIVITY

作者：Heinicke Joachim^*; Lach Joanna; Basvani Kaleswara R; Peulecke Normen; Jones Peter G; Koeckerling Martin

来源：Phosphorus, Sulfur, and Silicon and the Related Elements, 2011, 186(4): 666-677.

DOI：10.1080/10426507.2010.514485

• Asymmetric phosphines
• ethylene oligomerization
• hybrid ligands
• nickel catalysis
• phosphino amino acids

One-pot three-component reactions of secondary or primary phosphines and primary amines with glyoxylic acid provide a wide variety of acyclic or cyclic phosphinoglycines, in the case of some chiral amines with high diastereoselectivity. The structure, hydrolysis, oxidation, coordination at M(CO)(5) (M = Cr, Mo, W), and use in nickel-catalyzed ethylene oligomerization were studied.

• 出版日期2011