A New Type of Red-emitting (La,Ca)OCl:Eu3+ Phosphors

作者:Kim Sun Woog; Jyoko Kazuya; Masui Toshiyuki; Imanaka Nobuhito*
来源:Chemistry Letters, 2010, 39(6): 604-606.
DOI:10.1246/cl.2010.604

摘要

Red-emitting phosphors, (La1-xCax)OCl:y%Eu3+ (0 <= x <= 0.17, 1 <= y <= 5), were synthesized in a single-phase form by a liquid-phase method and photoluminescence properties were characterized. The excitation peak intensity of the phosphor was increased with Ca2+ doping into the LaOCl lattice, corresponding to the successful enhancement of the emission intensity. The maximum emission intensity was obtained for (La1-xCax)OCl:y%Eu3+, where it was 63% of that of a commercial Y2O3:Eu3+ phosphor.

  • 出版日期2010-6-5