A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure

作者：Oohora Koji; Onuma Yoshitaka; Tanaka Yuta; Onoda Akira; Hayashi Takashi

来源：Chemical communications, 2017, 53(51): 6879-6882.

DOI：10.1039/c7cc02678a

Supramolecular assembly of an engineered hemoprotein with an externally-attached heme moiety via an azobenzene or stilbene linker demonstrates drastic structural transitions between two distinct forms: the thermodynamically stable fiber-type assembly and the kinetically trapped metastable micelle-type assembly induced by transient thermal stimulus.

• 出版日期2017-6-28