Determination of hydroxyl radicals from photolysis of Fe(III)-pyruvate complexes in homogeneous aqueous solution

作者：Wang, Lei; Zhang, Changbo; Wu, Feng^*; Deng, Nansheng; Glebov, Evgeni M.; Bazhin, Nikolai M.

来源：Reaction Kinetics and Catalysis Letters, 2006, 89(1): 183-192.

DOI：10.1007/s11144-006-0101-8

• pyruvate
• iron(III)
• hydroxyl radicals
• photolysis

Benzene was used as a probe to detect (OH)-O-center dot produced by photolysis of Fe(III)-pyruvate complexes in a homogeneous system. The Fe(III)-Pyr system was found to be not catalytic. Influence of pH, temperature, as well as the concentration of Fe(III) and pyruvate (Pyr) on the (OH)-O-center dot yield was investigated.

• 出版日期2006-10
• 单位武汉大学