A regioselective synthesis of poly-substituted aryl triflones through self-promoting three component reaction

作者：Yanai Hikaru; Fujita Masaya; Taguchi Takeo^*

来源：Chemical communications, 2011, 47(25): 7245-7247.

DOI：10.1039/c1cc12093j

In the absence of any additional catalysts, the reactions of (CF(3)SO)(2)CH(2), aldehydes, and 1,3-dienes gave gem-bis(triflyl)cyclohexenes in excellent yields with high regioselectivity. gem-Bis(triflyl)cyclohexene products can be easily converted to the corresponding aryl trifluoromethyl sulfones.

• 出版日期2011