A behavioural difference between an iron(II) grafted polyphosphazene and its small molecule cyclophosphazene analogue

作者：Davidson Ross J; Ainscough Eric W^*; Brodie Andrew M; Waterland Mark R; Allcock Harry R; Hindenlang Mark D; Moubaraki Boujemaa; Murray Keith S; Gordon Keith C; Horvath Raphael; Jameson Guy N L

来源：Inorganic Chemistry Communications, 2013, 37: 158-161.

DOI：10.1016/j.inoche.2013.09.056

• Polyphosphazene
• Iron(II)
• Spin-crossover

Mossbauer and electronic absorbance spectroscopy along with variable temperature magnetic moment measurements demonstrate that a cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety (1) and its polyphosphazene analogue (2) differ significantly in magnetic behaviour.

• 出版日期2013-11