Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis

作者:Matsumoto Arimasa; Ozawa Hirokazu; Inumaru Ayako; Soai Kenso*
来源:New Journal of Chemistry, 2015, 39(9): 6742-6745.
DOI:10.1039/c5nj01459j

摘要

Retgersite, nickel sulfate hexahydrate, forms a chiral crystal with space group P4(1)2(1)2 or P4(3)2(1)2. A chiral crystal of nickel sulfate hexahydrate was found to act as a chiral initiator of asymmetric autocatalysis, affording highly enantiomerically enriched pyrimidyl alkanols with the corresponding absolute configurations.

  • 出版日期2015