First magnets based on thiocyanato-bridges

作者：Mousavi Maliheh; Bereau Virginie; Duhayon Carine; Guionneau Philippe; Sutter Jean Pascal^*

来源：Chemical communications, 2012, 48(80): 10028-10030.

DOI：10.1039/c2cc33877g

2-D NCS-bridged {3d-4d} molecule-based magnets, formed by reaction of [Mo-III(NCS)(6)](3-) with either Ni-II or Co-II complexes, have been found to exhibit magnetic ordering with T-C = 39 K for {Co3Mo2} while {Ni3Mo2} has a non-magnetic ground state as a result of exact compensation by the individual sub-lattices.

• 出版日期2012