A new layered vanadate complex with a tunnel structure: [{Cu(mbpy)}2V8O21] (mbpy=4,4';-dimethyl-2,2';-bipyridine)

作者：Han Zhangang^*; Wu Jingjing; Chai Tao; Zhai Xueliang

来源：Journal of Coordination Chemistry, 2010, 63(10): 1690-1699.

DOI：10.1080/00958972.2010.490295

• Polyoxometalate
• Vanadate
• Layered structure
• Hybrid
• Copper

A new vanadate with a tunnel structure [{Cu(mbpy)}2V8O21] (1) (mbpy = 4,4';-dimethyl-2,2';-bipyridine) has been synthesized hydrothermally. X-ray crystal analysis reveals that 1 exhibits a layered structure constructed from {V8O21}n layers grafted with secondary metal coordination groups of Cu-mbpy. The thermogravimetric analysis and electrochemistry of 1 are also reported.

• 出版日期2010
• 单位河北师范大学